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Additional info for Mass transfer with chemical reaction in multiphase systems (NATO ASI series) Volume I: Two-Phase Systems

Sample text

12 does not have predictive value, since the value of the film thickness 0 (into which the whole ignorance about the true fluid mechanics has been lumped) is not known. 12 can then be used to express I as a function of ki. The value of the latter will of course need to be estimated on the basis of available correlations for classical mass transfer. The film theory has an important drawback. Although, the value of 0 is not known, one should regard it as uniquely dete£ mined by the hydrodynamics of the liquid phase.

However, there is an upper bound to the possible rate enhancement, which~is discussed in qualitative terms in the following. The assumption that fugacity is continuous across an inter face, holds also for chemically-reactive systems. /H (5) ~ where H is Henry's law constant. However, the liquid at the interface is in general not in chemical equilibrium with the gas phase; the value of a, the total concentration of the transferring component (in both physically dissolved and chemically combined forms) at the interface is not the value a~ corresponding to equilibrium with a.

Any chemical reaction taking place in the liquid phase can influence the mass transfer rate only if it takes appreciably in the gas-liquid interface say at x < Q. Values of" <5 of practical interest can be calculated from Eq's. 12 and 15; taking for D a typical value of cm 2 /sec, one obtains 2 x 10- 4 < <5 < 4 x 10- 4 cm (56) A reaction place on the liquid-solid interface could there fore result in appreciable rate enhancement only if a significant number of solid particles are present at distances from the gasinterface less than 10-4 cm.

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