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Additional info for Chemical Design of Responsive Microgels
Polymerization of Hydrophilic Monomers in Inverse Miniemulsion. . . . . . . . . . . Gelatin Nanoparticles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Gels for Release . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Hyperbranched Polymers in Miniemulsion . . . . . . . . . . . . . . . . . . . . . . . . . Amphiphilic Copolymers .
However, it is of interest to use a minimum concentration of crosslinking agent, at which all chains are crosslinked and no free chains are left behind within the particles. It has been demonstrated that, independent of the molecular weight distribution of the gelatin used, stable nanoparticles can be produced with a small amount of surfactant (see Fig. 4 left). After the synthesis, the organic solvent can be removed and the particles transferred to an aqueous continuous phase. The stability of the dispersion, particle size, and the efficiency of crosslinking (by analyzing the non-crosslinked free chains) have been studied in detail.
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