By Charles E. Carraher, James A. Moore
content material: Polymer amendment : a few difficulties and chances : components wanting learn / Charles E. Carraher, Jr. and Minoru Tsuda --
Aminated polystyrene-copper complexes as oxidation catalysts : the impression of the measure of substitution on catalytic task / G. Challa, A.J. Schouten, G. Ten Brinke, and H.C. Meinders --
Kinetics of intramolecular cross-linking and conformational homes of cross-linked chains / N.A. Platé, O.V. Noah, I.I. Romantzova, and Yu. A. Taran --
Chemical amendment of polyvinyl chloride and similar polymers / M. Okawara and Y. Ochiai --
Low-temperature amendment of polymers / Charles E. Carraher, Jr. --
Incorporation of steel ions into polyimides / L.T. Taylor, V.C. Carver, T.A. Furtsch, and A.K. St. Clair --
Biologically lively amendment of polyvinyl alcohol : the response of phenyl isocyanate with polyvinyl alcohol / Charles G. Gebelein and Keith E. Burnfield --
Vinyl polymerization (383): radical polymerization of vinyl monomer with an aqueous answer of polystyrenesulfonate or polyvinylphosphonate / M. Imoto, T. Ouchi, M. Sakae, E. Morita, and T. Yamada --
Chemical adjustments of polymers : mechanistic features and particular homes of the derived copolymers / J.C. Galin --
Conversion of graft polyacrylamide to amines through the Hofmann and Mannich reactions / R.J. Eldridge --
Polymer-copper catalysts for oxidative polymerization of phenol derivatives / E. Tsuchida and H. Nishide --
constitution, mechanism, and reactivity of organotin carboxylate polymers / K.N. Somasekharan and R.V. Subramanian --
Photocross-linking of 1,2-polybutadiene by way of fragrant azide / Tsuguo Yamaoka, Takahiro Tsunoda, Ken-Ichi Koseki, and Isao Tabayashi --
amendment of electric houses in poly-N-vinylcarbazole by way of UV light-thermally influenced present / H. Kitayama, T. Fujimoto, M. Yokoyama, and H. Mikawa --
a unique amendment of polymer surfaces by means of photografting / Shigeo Tazuke, Takao Matoba, Hitoshi Kimura, and Takeshi Okada --
Acid results within the radiation grafting of monomers to polymers, fairly polyethylene / John L. Garnett and Nguyen T. Yen --
Synthesis and homes of photopolymer printing plates for a printing grasp plate via amendment of polyvinyl alcohol / Hisashi Nakane, Toshimi Aoyama, Hiroshi Takanashi, Bonpei Kato, and Hiroyuki Tohda --
Sensitized photodegradation of polymethylmethacrylate / Minoru Tsuda, Setsuko Oikawa, Yohichi Nakamura, Hideo Nagata, Akira Yokota, Hisashi Nakane, Toshiro Tsumori, and Yasuaki Nakane --
The impression of photolysis at the biodegradation of a few step-growth polymers / Samuel J. Huang, Catherine Byrne, and Joseph A. Pavlisko --
Acceleration of radiation-induced cross-linking of polyethylene via chlorotrifluoroethylene / T. Kagiya, T. Wada, N. Yokoyama, and H. Ono --
impact of discharge frequency at the plasma polymerization of ethane / S. Morita, S. Ishibashi, M. Shen, and A.T. Bell --
Chiral organofunctional polysiloxanes : synthesis, homes, and functions / Ernst Bayer and Hartmut Frank --
Synthesis of poly-L-lysine containing nucleic acid bases / Y. Inaki, T. Ishikawa, and ok. Tayemoto --
Homogeneous resolution reactions of cellulose, chitin, and different polysaccharides / C.L. McCormick, D.K. Lichatowich, J.A. Pelezo, and K.W. Anderson --
amendment of cotton with tin reactants / Charles E. Carraher, Jr., Jack A. Schroeder, Christy McNeely, Jeffrey H. Workman, and David J. Giron --
floor changes of cellulose and polyvinyl alcohol, and backbone of the skin density of the hydroxyl staff / T. Matsunaga and Y. Ikada --
Simultaneous interpenetrating networks in accordance with castor oil elastomers and polystyrene : a evaluate of a world application / L.H. Sperling, N. Devia, J.A. Manson, and A. Conde --
Flammability of phosphorus-containing fragrant polyesters : a comparability of additions and comonomer flame retardants / Robert W. Stackman --
digital cooperativity in new [pi]-donor polymers ready via amendment reactions of poly(vinylbenzyl chloride) / Frank B. Kaufman, Edward M. Engler, and Dennis C. eco-friendly --
constitution and estate amendment of m-carborane siloxanes / Edward N. Peters --
Siloxane-modified polyarylene carbonates / Harold Rosenberg, Tsu-Tzu Tsai, Boris D. Nahlovsky, and Csaba A. Kovacs --
Polymer-filler composites via in situ graft copolymerization : polyethylene-clay composites / Norman G. Gaylord, Hans Ender, Linwood Davis, Jr., and Akio Takahashi.
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Extra resources for Modification of Polymers
Example text
T o c a l c u l a t e the c r o s s - l i n k i n g k i n e t i c s ; 3. t o c a l c u l a t e t h e c r o s s - l i n k s n u m b e r d i s t r i b u t i o n ; 4. t o c a l c u l a t e d i m e n s i o n s o f p a r t i a l l y cross-linked macromolecular coils; 5. to c o n s i d e r the i n f l u e n c e of the r e a c t i v e groups d i s t r i b u t i o n a n d HMD. B e s i d e s we h a v e shown t h e p o s s i b i l i t y t o a p p l y t h e r e s u l t s of model c a l c u l a t i o n s t o some e x p e r i m e n t a l data and c o n s i d e r a s i m p l e approximate approach to the calc u l a t i o n o f dimensions of p a r t i a l l y c r o s s - l i n k e d c o i l s and c r o s s - l i n k i n g k i n e t i c s .
Was treated with Chloramine T at 60 °C i n DMF, s u l f i l i m i n e type polymer (13,V(S=N), 965 cm" ) was obtained, which also affords the method to obtain a sulfoxide polymer without sulfone moiety on heating a dioxane solution containing small amounts of hydrogen c h l o r i d e . A donor-type polymer 13, gave complex polymer (14) by the reaction with BF-CH-CH methanol i n methylene c h l o r i d e , j 2 which r e v e r s i b l y returned to the s u l f i l i m i n e \£ with triethylamine.
So E d w a r d s e t a l . [ l l j s u g g e s t e d t h e f o l l o w i n g a p p r o x i m a t e r e l a t i o n s h i p b a s e d on t h e t h e r m o d y n a m i c c o n s i d e ration : — ~o - 2 - — 2 m. m + \- J T h i s r e l a t i o n i s too i n a c c u r a t e and g i v e s results v e r y f a r f r o m t h e ? onte C a r l o o n e s . G o r d o n e t a l . £l2]_/aave m o d i f i e d t h i s r e l a t i o n s h i p : T 72 T h i s o n e i s much b e t t e r , b u t t h e d i s c r e p a n c i e s are rather essential.