By F. C. Nachod
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Example text
15 is a comparison of the theory with the experimental results. From this figure it is apparent that Na + behaves essentially as predicted but that Cl- is more highly concentrated in the interlayer than the theory predicts. This lack of agreement in the case of Clmay be due in part to the approximation i± = i't employed as explained by Bernstein. 15 Crystal-melt equilibria We now consider the equilibria established between crystals and a complex solution of molten oxides or silicates. Later on we shall consider numerous systems of this sort in the physical chemistry of natural magmas.
9, shows the observed distribution of manganese. 12 2 Equilibrium of mineral systems The influence of one element on the distribution of another was first studied in detail by Kretz (1959). A particularly fine illustration is represented by his study of the distribution of vanadium among coexisting biotites, hornblendes, and garnets. 12. 1 0 shows the orderly distribution for biotite and hornblende. 11) shows an apparent enormous scatter, and on the basis of vanadium alone one could be inclined to doubt that equilibrium was attained here.
11 V203 distribution between coexisting garnet and biotite. (After Kretz, 1959. 24 in garnet Effect ofCa concentration on the V20 3 distribution between biotite and garnet. (After Kretz, 1959. 12 The equilibrium of the average metamorphic mineral assemblage requires the simultaneous consideration of all the various types of reactions discussed thus far. As an illustration of such an equilibrium we again use the iron-formation assemblages, since they are of only moderate complexity. Kranck (1961) has found the following association in Quebec: ~ :§.