By R.E. Banks (Eds.)

Content material:
Foreword

, Page ix, George A. Olah
Editor's preface

, Pages xi-xiv, Eric Banks
About the editor

, Pages xv-xvi
Chapter 1 - Following fluorine in nuclear gas manufacture at BNFL

, Pages 1-13, Malcolm J. Atherton
Chapter 2 - having a look in on fluorine chemistry in Russia and Ukraine

, Pages 15-27, Derek L. Averre
Chapter three - 40 years of fluorine chemistry: King's university, Newcastle (1954–57); The collage of British Columbia (1958–66); Princeton college (1966–69); And the college of California at Berkeley (1969–98)

, Pages 29-55, Neil Bartlett
Chapter four - Contribution to the perpetuation of Moissan's reminiscence: The Moissan Prize

, Pages 57-65, Roland Bougon
Chapter five - Organofluorine chemistry in Novosibirsk (Siberia)

, Pages 67-80, Gerald M. Brooke
Chapter 6 - The Iowa connection

, Pages 81-121, Donald J. Burton
Chapter 7 - Organofluorine chemistry within the collage of Durham, UK

, Pages 123-137, Richard D. Chambers
Appendix 7.1 - occupied with fluoroaromatic chemistry

, Pages 138-141, Gerald M. Brooke
Appendix 7.2 - Adventures with fluorinated dienes

, Pages 142-145, W.J. Feast
Appendix 7.3 - Fluorinated bio-organic compounds

, Pages 146-148, David O'Hagan
Chapter eight - by no means say no to a challenge

, Pages 149-166, Karl O. Christe
Chapter nine - The anionic aspect of fluorine chemistry

, Pages 167-174, James H. Clark
Chapter 10 - Laporte and its fluoride businesses

, Pages 175-178, Alan E. Comyns
Chapter eleven - Fluorine chemistry—A chemical Gardener's paradise

, Pages 179-202, Darryl D. Desmarteau
Chapter 12 - Pursuing fluorine chemistry in Poland

, Pages 203-214, Wojciech Dmowski
Chapter thirteen - Biographical caricature of Paul Tarrant

, Pages 215-224, William R. Dolbier Jr.
Chapter 14 - Fluoropolymers, reliable nitroxides and perfluoroalkylation

, Pages 225-239, Kalathil C. Eapen
Chapter 15 - Fluorine chemistry in Italy

, Pages 241-246, Giampaolo P. Gambaretto
Chapter sixteen - Fluorine chemistry at Leicester

, Pages 247-260, John H. Holloway, Eric G. Hope
Chapter 17 - chinese language study in organofluorine chemistry

, Pages 261-270, Chang-Ming Hu, Wei-Yuan Huang
Chapter 18 - Fluorine chemistry in Japan

, Pages 271-281, Yoshiro Kobayashi, Takeo Taguchi, Takashi Abe
Chapter 19 - the invention of profitable direct fluorination syntheses: 3 ears of elemental fluorine response chemistry

, Pages 283-296, Richard J. Lagow
Chapter 20 - Flogging the fluorocarbons

, Pages 297-320, David M. Lemal
Chapter 21 - Adventures of a fluorine chemist at DuPont

, Pages 321-338, William J. Middleton
Chapter 22 - Fluorine chemistry: The ICI legacy

, Pages 339-383, Richard L. Powell
Chapter 23 - Fluorocarbon emulsions—Designing an effective travel carrier for the breathing gases—The so-called ‘Blood Substitutes’

, Pages 385-431, Jean G. Riess
Chapter 24 - a few facets of fluorine chemistry in Göttingen

, Pages 433-447, Herbert W. Roesky
Chapter 25 - Fluorocarbon steel compounds—Role types in organotransition steel chemistry

, Pages 449-462, F. Gordon, A. Stone
Chapter 26 - fragrant fluorine chemistry at Salford

, Pages 463-473, Hans Suschitzky, Basil J. Wakefield
Chapter 27 - Fluorine chemistry on the collage of Birmingham—A cradle of the topic within the UK

, Pages 475-489, John Colin Tatlow
Chapter 28 - The belated hexafluorobenzene papers of Yvonne Désirant

, Pages 491-497, Dirk Tavernier
Chapter 29 - Highly-toxic fluorine compounds

, Pages 499-538, Christopher M. Timperley
Chapter 30 - From complicated fluorides to CFC choices — An account of fluorine chemistry at Glasgow

, Pages 539-556, John M. Winfield
Appendix 30.1 - memories of early days within the Cambridge Inorganic Lab

, Pages 557-558, A.A. Woolf
Appendix 30.2 - Chemistry at Birmingham within the 1960s

, Pages 559-560, Mary Mercer
Chapter 31 - improvement of inorganic fluorine chemistry in Slovenia

, Pages 561-569, Boris emva
Chapter 32 - Going with the fluo

, Pages 571-607, Ronald Eric Banks
Appendix 32.1 - memories of fluorochemical learn at Avonmouth

, Pages 608-611, Anthony ok. Barbour
Appendix 32.2 - Fluorine chemistry

, Pages 612-614, Haydn Sutcliffe
Appendix 32.4 - Fluorine

, Pages 618-620, Russell P. Hughes
Appendix 32.5 - India to the us through UMIST

, Pages 621-624, Sharique S. Zuberi
Name index

, Pages 625-634
Subject index

, Pages 635-637
Establishment index

, Pages 639-643

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Additional resources for Fluorine Chemistry at the Millennium. Fascinated by Fluorine

Example text

O'Donnell's lab in early 1965, I had him attempt a clean preparation of XePtF6 from O2PtF6 with high pressure Xe (using sodium elsewhere in the pressure vessel as 'getter' for the 02). The projected reaction failed. When a combination of Xe with F2 was applied to PtF5 to attempt to form the crystalline product of the Xe + PtF6 reaction, he found that he could easily (F2 at 10 psi at 180-220 ~ make Xe(VI) complexes, one of which was isolated in single crystal form and proved [55] the formulation XeF+PtF6 9 Xe + 3F2 + PtF5 ~ XeF+PtF6 The poor F- donor properties of XeF4 There was never a hint of XeF4 complexes of Pt(V) in this work of Stewart, but the existence of Xe(PtF6)2 proved that XeF2 derivatives of Pt(V) should exist.

The material that had been identified by two groups [19, 20] as iridium tetrafluoride, IrF4, was eventually shown [21] by my co-worker P. R. Rao at UBC to be IrFs. Rao also prepared (independently of John Holloway) [22] RhF5 and genuine [23] IrF4. I left the Robinson research group in July 1957 in order to take up a post not far from Newcastle as Senior Chemistry Master at the Duke's School in Alnwick (Northumberland), this job excusing me from military service. A little over one year later I was offered and accepted an appointment at the University of British Columbia in Vancouver, where I was to spend the next eight years.

It was not until the work of Christe and Bougon [84], using KrF2 as oxidant, that the latter molecule became known. The successful preparation of OsOF5 stimulated a search for IOF5. The existence of IOF5 was established independently in three different laboratories almost simultaneously [85-87]. ) My co-worker in the UBC discovery [86] was an undergraduate student, L. E. Levchuk, who made it by treating IF7 with various oxides, including water, and showed that all previous structural studies of IF7 were suspect, as a consequence of the close physical similarity of IOF5 to IF7.

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