By Henry Taube
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Additional info for Electron Transfer Reactions of Complex Ions in Solution
Example text
Rutenberg and H. Taube, / . Chem. Phys. 20, 825 (1952). 12. H. R. Hunt and H. Taube, / . Am. Chem. Soc. 20, 2692 (1958). 13. 0 V. T h e driving force for the reduction of the Co(III) complex derives in large part from the affinity of N H 8 for H + . However, the kinetic data show that H + does not engage N H a in the activated complex for the reduction of Co(III). T h e value of E° entered is a "kinetic" value as estimated by A. Haim and H. Taube, J. Am. Chem. Soc. 85, 1 (1963). 14. R. E. Connick, private communication.
REFERENCES 1. G. T. Seaborg, Chem. Rev. 27, 199 (1940). 2. Symposium on Electron Transfer Processes, / . Phys. Chem. 56, 801-910 (1952). 46 I I . ACTIVATED COMPLEXES FOR ELECTRON TRANSFER 3. Comment by H. C. Brown following the paper by J. Silverman and R. W. Dodson, in which the influences of anions on rates of electron transfer were discussed, / . Phys. Chem. 56, 896 (1952). 4. W. F. Libby, / . Phys. Chem. 56, 863 (1952), and subsequent discussion. 5. A. M. Zwickel and H. Taube, / . Am. Chem.
Am. Chem. Soc. 85, 1 (1963). 14. R. E. Connick, private communication. 15. T h e notation Ce(IV) rather than Ce 4 f is chosen because the ion hydrolyzes quite strongly in acid, and the constitution of the ion is sensitive to acidity. 16. O. Schmitz-Dumont, H. Brokopf, and K. Burkhardt, Z. Anorg. Allgem. Chem. 295, 7 (1958). 17. H. Baldwin and H. Taube, / . Chem. Phys. 33, 206 (1960). 18. R. E. Connick and D. N . Fiat, J. Chem. Phys. 39, 1349 (1963). 19. R. E. Connick and D . N. Fiat, / . Chem. Phys.